Robust spin crossover platforms with synchronized spin switch and polymer phase transition
F. Novio, E. Evangelio, N. Vazquez-Mera, P. Gonza´lez-Monje, E. Bellido, S. Mendes, N. Kehagias, D. Ruiz-Molina
Sci. Rep., 3, 1708, (2013)
Abstract: The idea of developing magnetic molecular materials into real functional electronic devices with low-cost and scalable techniques appeared with the emergence of the field several years ago. Today, even though great advances have been done with this aim, the promise of a functional device working at the micro-/nanoscale and at room temperature has unfortunately not completely materialized yet, as their use still strongly depends on the fabrication methodology of a robust device that can be handled and integrated without compromising their functionality. Here we propose the use of polymeric matrices as a platform for the development of such robust switchable structures exhibiting reproducible results independently of the dimension -from macro to micro-/nanoscale- and morphology -from thin-films to nanoparticles and nanoimprinted motives- while allowing to induce an irreversible hysteresis, reminiscent of a non-volatile memory, by synchronization with the polymer phase transition.